Behavior of simulated spent fuel in subcritical water

Mineo, Hideaki; Suzuki, Tadashi; Morita, Yasuji

Proceedings of 2nd International Symposium on Supercritical Fluid Technology for Energy and Environment Applications (Super Green 2003), p.334 - 338, 2003/00

Behavior of spent nuclear fuel in subcritical water was investigated to look at the feasibility of fission-products (FPs) separation without organic solvent. The study employed unirradiated UO particles simulating spent fuel burned up to 45,000MWdt, which includes FP elements in oxide form: Sr, Zr, Mo, Ru, Rh, Pd, Ag, Ba, La, Ce, Pr, Nd and Sm. Also, alloy particles consisted of Mo, Ru, Rh and Pd were prepared to simulate the metallic phase of FP. 12.728 g of the fuel and 52 mg of the alloy were placed in a 10 ml pressure vessel, where subcritical water was fed. The temperature was 523, 573, 623 and 663K, while the pressure was kept at 29MPa. Dissolved fraction decreased with elevating temperature. It was found that more than 5% of Ba, Mo and Pr were respectively dissolved. The dissolved fraction of Sr and Rh were about 1%, and about 0.3% for Zr. La, Ce, Nd and Sm, indicated almost the same result as U, which was about 0.1%. It was suggested that the subcritical water could separate portion of FP. Further study would be carried out with smaller-sized fuel.